cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ2 N,N′]bis(dimethyl sulfoxide-κO)cadmium
نویسنده
چکیده
The complete mol-ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl-sulfoxide mol-ecules. The resulting N(4)O(2) donor set displays a distorted trigonal-prismatic coordination geometry. The S atom and methyl groups of dimethyl-sulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features inter-molecular N-H⋯N and N-H⋯O hydrogen bonds that lead to the formation of layers in the ab plane.
منابع مشابه
Bis(2,2′-bi-1H-imidazole-κ2 N 3,N 3′)bis(dimethyl sulfoxide-κO)copper(II) bis(tetrafluoridoborate)
In the title copper(II) salt, [Cu(C(6)H(6)N(4))(2)(C(2)H(6)OS)(2)](BF(4))(2), the Jahn-Teller distorted octa-hedral coordination sphere of copper is formed from four 2,2'-bi-1H-imidazole N atoms and two dimethyl sulfoxide O atoms. The Cu atom lies on a center of inversion. N-H⋯O and N-H⋯F hydrogen bonds give rise to a one-dimensional structure. The BF(4) (-) anion is disordered over two sites i...
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